Wear resistant steels, such as low alloy steels, are widely used in multiple industrial applications. The wear resistance of this class of materials is primarily influenced by the microstructure formed during heat treatment. Heat treatment is a critical step during the production of wear resistant steels, and can involve a range of processes including phase transformations, precipitation and/or decomposition of phases. In this article, we examine the effect of heat treatment on the microstructure and mechanical properties of low alloy wear resistant steels and discuss how the different stages of the heat treatment process affect their wear resistance.
The low alloy wear resistant steels typically contain a range of alloys, with each alloy influencing the microstructure of the material and the properties it can achieve. Commonly used alloys include carbon, manganese, silicon and often metal carbides (such as chromium, vanadium, tungsten and molybdenum). These alloys are typically added in order to strengthen the material, as well as enhance its resistance to wear and abrasion.
The microstructure of low alloy wear resistant steels is mainly composed of ferrite, austenite and carbide phases. Ferrite is a hard, brittle material composed of iron and a small amount of carbon, while austenite is a metallic, ductile material composed of iron and carbon, and is the main constituent of steel. The hard carbide particles (such as tungsten carbide) present in the alloy act to increase wear resistance.
Figure 1: Microstructure of Low Alloy Wear Resistant Steel
The heat treatment procedure for low alloy wear resistant steels typically involves four stages (see Figure 2). During the first stage, the material is heated to above its Austenitizing Temperature. This temperature is typically around 815°C (1,500°F). At this temperature, the material begins to transform from ferrite and carbides into a single-phase austenite. During the second stage, the material is rapidly cooled (usually by quenching in a hot oil bath) to form a more stable and homogenous austenite matrix. This involves transforming some of the austenite back into ferrite and carbides.
The third stage of the heat treatment process is tempering, which involves heating the material to a temperature below its Austenitizing Temperature but above the Ms Temperature (the temperature at which the material completely transforms from austenite to ferrite). This process allows the precipitation and/or decomposition of the alloying elements, which helps to further strengthen the material and increase its wear resistance. Finally, the last stage is accelerated cooling, which is controlled cooling of the material in order to retain the desired microstructure and mechanical properties.
Figure 2: Heat Treatment Process of Low Alloy Wear Resistant Steel
During the heat treatment process, the microstructure of low alloy wear resistant steels undergoes a drastic transformation. The initial microstructure is predominantly composed of ferrite and carbides, with minimal austenite. The carbides are extremely hard and abrasion-resistant, which provide the material with its initial wear resistance. As the material is heated, the ferrite and carbides begin to transform into a single-phase austenite matrix (see Figure 3). The austenite matrix helps to reduce the grain size in the material and allows for the easier formation of carbides at a later stage.
Once the material has been fully transformed into austenite, it is rapidly cooled to form a more stable and homogenous microstructure. This rapid cooling helps to preserve the newly formed austenite and prevent it from transforming back into ferrite and carbides. During the tempering stage, some of the austenite transforms back into ferrite and carbides, which further strengthens and toughens the material.
Finally, the material is rapidly cooled to retain its desired mechanical properties. During this stage, the austenite is cooled at a rate sufficient to prevent it from recrystallizing, while allowing the carbide to remain in a fine, homogenous state. This helps to create a dense and homogenous microstructure with a finer grain size and a more uniform distribution of hard carbide particles, resulting in increased hardness and wear resistance (see Figure 4).
Figure 3: Microstructure of low alloy wear resistant steel before and after heat treatment
Figure 4: Microstructure of low alloy wear resistant steel with a homogenous distribution of hard carbide particles
In conclusion, the heat treatment process is essential for the production of wear resistant low alloy steels. During the heat treatment process, the microstructure undergoes a dramatic transformation, which affects the material’s wear resistance. The rapid cooling helps to preserve the newly formed austenite and the tempering helps to further strengthen the material. The accelerated cooling helps to create a dense and homogenous microstructure with a finer grain size and a more uniform distribution of hard carbide particles, resulting in increased hardness and wear resistance.
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